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Home Magazine issues April 2024

Beneath the Harvest

Dr. Patrick Freeze by Dr. Patrick Freeze
March 29, 2024
in April 2024, Soil & plant health
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Unearthing Solutions to Heavy Metal Contamination

Dr. Patrick Freeze

Heavy metals pose a significant and insidious threat to the health and sustainability of our agricultural systems. From arsenic and lead residues from historical practices to ongoing contamination by cadmium and mercury from modern industries, these toxic elements compromise the safety and integrity of our food supply. This article explores the origins of heavy metal contamination, their damaging effects, and the innovative strategies to reduce their uptake in plants and subsequent exposure to humans.

Occurrence and Sources

Heavy metals exist naturally within the Earth’s crust, mostly in forms unavailable to plants and humans. However, human activity has drastically accelerated their release into the environment. The Resource Conservation and Recovery Act identifies eight metals of particular concern: arsenic, lead, cadmium, chromium, mercury, selenium, silver, and barium. Zinc is also a prevalent heavy metal contaminant given its use in agriculture and in metal alloys. These metals can enter agricultural soils through various pathways, including atmospheric deposition, industrial activities, soil disturbance through development, pesticide use, and wastewater irrigation.

Of all these activities, industry remains the major source of contamination and exposure risks, releasing lead, zinc, and cadmium, to name a few. Mining generates vast amounts of waste containing heavy metals that contaminate surrounding air, water, and soil. For example, mercury and arsenic pollution are often linked to gold mining activities. In other industrial sectors, inadequate treatment or the careless disposal of waste and sewage sludge releases a broad spectrum of heavy metals into agricultural environments. These sources can contribute zinc (up to 500 mg/kg in manure), chromium (10-100 mg/kg in compost), and trace amounts of silver and nickel to soils.

Heavy MetalAnthropogenic SourcesEPA Limits: Agricultural Soil (mg/kg)EPA Limits: Residential Soil (mg/kg)EPA Limits: Drinking Water (μg/L)Concentration Ranges in Contaminated Sites (mg/kg)
Arsenic (As)Pesticides, wood preservatives, mining180.680.0550-600+
Lead (Pb)Battery manufacturing, industrial activities1204001510-500
Cadmium (Cd)Industrial emissions, phosphate fertilizers327.11.81-30
Chromium (Cr)Electroplating, leather tanningN/A0 (total)0.3 (hexavalent)Varies widely; 100-2000
Mercury (Hg)Coal burning, gold miningN/A110.631-10
Selenium (Se)Coal burning, mining, smelting, ag runoff0.523901001-10
Zinc (Zn)Mining, smelting, sewage sludge16023000600050-300
Silver (Ag)Photographic processes, electrical contacts56039094Less common; up to 5
Barium (Ba)Mining, drilling, alloy production, smeltingN/A1500038001000+
Table 1. Main heavy metals and metalloids

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Tags: Agricultural sustainabilityHeavy metal contaminationSoil remediation
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Dr. Patrick Freeze

Dr. Patrick Freeze

Patrick Freeze is a soil health scientist, research and development manager, and technical specialist at Ward Labs. He earned his Ph.D. in soil chemistry from Washington State University where he studied soil health and heavy metal chemistry as a USDA NIFA Needs Fellow and in Thailand as a U.S. Fulbright Scholar.

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